全文获取类型
收费全文 | 1099篇 |
免费 | 136篇 |
国内免费 | 741篇 |
专业分类
安全科学 | 73篇 |
废物处理 | 117篇 |
环保管理 | 97篇 |
综合类 | 1145篇 |
基础理论 | 174篇 |
污染及防治 | 338篇 |
评价与监测 | 26篇 |
社会与环境 | 3篇 |
灾害及防治 | 3篇 |
出版年
2023年 | 13篇 |
2022年 | 25篇 |
2021年 | 27篇 |
2020年 | 44篇 |
2019年 | 59篇 |
2018年 | 48篇 |
2017年 | 47篇 |
2016年 | 64篇 |
2015年 | 100篇 |
2014年 | 109篇 |
2013年 | 106篇 |
2012年 | 140篇 |
2011年 | 120篇 |
2010年 | 104篇 |
2009年 | 123篇 |
2008年 | 82篇 |
2007年 | 150篇 |
2006年 | 130篇 |
2005年 | 96篇 |
2004年 | 67篇 |
2003年 | 58篇 |
2002年 | 52篇 |
2001年 | 45篇 |
2000年 | 30篇 |
1999年 | 22篇 |
1998年 | 34篇 |
1997年 | 23篇 |
1996年 | 11篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 20篇 |
1992年 | 3篇 |
1991年 | 6篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有1976条查询结果,搜索用时 672 毫秒
121.
122.
随着城市垃圾焚烧工程的发展,国家对焚烧后尾气的处理技术提出了越来越高的要求。基于“表面过滤”理论的Gore过滤技术,不但为粉尘排放达到欧洲标准提供了技术保障,而且为脱酸/硫的后续反应提供了反应界面,在实际应用中可以有效节约反应剂。 相似文献
123.
膜过滤-气相色谱法测定涂料中的苯系物、环己酮和甲苯二异氰酸酯 总被引:1,自引:0,他引:1
采用膜过滤-气相色谱法测定涂料中的苯系物、环己酮和甲苯二异氰酸酯(TD I)。用7种规格的石英毛细管色谱柱对混合标准溶液和涂料试样进行了分析实验,实验结果表明,不同属性的涂料试样添加固定量的正十四烷作内标物,经膜过滤净化后,苯系物、环己酮和TD I可采用DB-1-3或DB-1-2色谱柱同时分离并测定。测试数据经多级校准曲线处理后涂料试样中苯系物、环己酮和TD I的加标回收率为98.6%~101.8%,各组分分析结果的变异系数均小于2.0%,检出限均小于1.50×10^-5g。 相似文献
124.
125.
针对一种高硬度富锶地下水,分别采用石灰和石灰-碳酸钠两种方法,利用药剂软化/超滤膜工艺对其进行软化处理,同时考察了药剂投量对出水锶含量的影响。结果表明,采用石灰软化/超滤膜法,Ca(OH)2最佳投加量为270 mg/L时,出水总硬度(以CaCO3计)由287.12 mg/L降低到96.44 mg/L,硬度去除率为66.41%,出水锶含量也由原水中的0.37 mg/L下降为0.21 mg/L;而采用石灰-碳酸钠软化/超滤膜法,Ca(OH)2和Na2CO3最佳投加量分别为270 mg/L、160mg/L时,出水总硬度降低到60.34 mg/L,硬度去除率达78.98%,锶含量仅为0.02 mg/L。2种处理方法出水总硬度均达到预期目标,石灰软化/超滤膜法可使出水锶含量满足富锶水的要求,而石灰-碳酸钠软化/超滤膜法则造成了对人体有益微量元素锶的大量损失。 相似文献
126.
氯酚与富里酸的缔合作用 总被引:1,自引:0,他引:1
本文用超滤膜方法证实氯酚与富里酸之间存在缔合作用,并计算出表观缔合常数在2.7*10^3--121*10^3ml.g^-1范围内。实验结果表明”PH、富里酸含量,氯酚取代氯原子个数都能够影响K值的大小。 相似文献
127.
Humic substances 总被引:2,自引:1,他引:1
Steinberg CE Meinelt T Timofeyev MA Bittner M Menzel R 《Environmental science and pollution research international》2008,15(2):128-135
GOAL, SCOPE AND BACKGROUND: Freshwater bodies which chemistry is dominated by dissolved humic substances (HS) seem to be the major type on Earth, due to huge non-calcareous geological formations in the Northern Hemisphere and in the tropics. Based on the paradigm of the inertness of being organic, direct interactions of dissolved HS with freshwater organisms are mostly neglected. However, dissolved organic carbon, the majority of which being HS, are natural environmental chemicals and should therefore directly interact with organisms. Major results that widened our perspective on humic substance ecology come from experiments with the compost nematode, Caenorhabditis elegans, which behaved contradictorily to textbook knowledge and provoked an in-depth re-consideration of some paradigms. APPROACH: To overcome old paradigms on HS and their potential interactions with organisms, we reviewed recent international literature, as well as 'grey' literature. We also include results from own ongoing studies. RESULTS: This review focuses on direct interactions of dissolved HS with freshwater organisms and disregards indirect effects, such as under-water light quenching. Instead we show with some macrophyte and algal species that HS adversely interfere with photosynthesis and growth, whereby closely related algal species show different response patterns. In addition to this, HS suppress cyanobacteria more than eukaryotic algae. Quinones in the HS appear to be the effective structure. Furthermore, HS can modulate the offspring numbers in the nematode C. elegans and cause feminization of fish and amphibians--they possess hormone-like properties. The ecological consequences of this potential remain obscure at present. HS also have the potential to act as chemical attractants as shown with C. elegans and exert a mild chemical stress upon aquatic organisms in many ways: induction of molecular chaperons (stress proteins), induction and modulation of biotransformation and anti-oxidant enzymes. Furthermore, they produce an oxidative stress with lipidperoxidation as one clear symptom or even stress defense strategy. Stronger chemical stresses by HS may even lead to teratogenic effects as shown with fish embryos; all physiological responses to HS-mediated stress require energy, which were compensated on the expense of yolk as shown with zebra fish embryos. One Finnish field survey supports the view of a strong chemical stress, as the weight yield in fish species decreases with increasing HS content in the lakes. DISCUSSION: HS exert a variety of stress symptoms in aquatic and compost organisms. According to current paradigms of ecotoxicology, these symptoms have to be considered adverse, because their compensation consumes energy which is deducted from the main metabolism. However, the nematode C. elegans looks actively for such stressful environments, and this behavior is only understandable in the light of new paradigms of aging mechanisms, particularly the Green Theory of Aging. In this respect, we discuss the mild HS-mediated stress to aquatic and compost organisms. New empirical findings with HS themselves and HS building blocks appear to be consistent with this emerging paradigm and show that the individual lifespan may be expanded. At present the ecological consequences of these findings remain obscure. However, a multiple-stress resistance may be acquired which improves the individual fitness in a fluctuating environment. CONCLUSIONS: It appears that dissolved HS have to be considered abiotic ecological driving forces, somewhat less obvious than temperature, nutrients, or light. PERSPECTIVES: The understanding of the ecological control by dissolved humic substances is still fragmentary and needs to be studied in more details. 相似文献
128.
129.
Allan IJ Nilsson HC Tjensvoll I Bradshaw C Næs K 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2393-2397
Integrative passive sampling with devices such as semipermeable membrane devices generally relies on rigs for month-long static exposures in water. We evaluate here whether mobile exposures of passive samplers can provide reliable estimates of dissolved contaminant concentrations. Mobile exposures were obtained by towing samplers fastened to the end of a benthic trawl net. Significant and reproducible absorption of polycyclic aromatic hydrocarbons during 5 h-long deployments was made possible by high sampling rates resulting from high water turbulences during towing at 1.2-1.5 knots. Sampling rates (72-215 L d−1) estimated from the dissipation of performance reference compounds were supported by in situ calibration with samplers exposed for a 30 days in the vicinity of the test site. Higher fluoranthene and pyrene absorption in samplers exposed to the trawling-induced sediment plume could be attributed to desorption from re-suspended sediments. This mode of exposure has the potential to be used in monitoring programmes. 相似文献
130.
采用芳香聚酰胺膜(NF-1#)、复合膜(NF-2#)和聚酰胺复合膜(NF-3#)深度处理棉针织品印染废水,考察了膜分离性能及膜污染情况的影响因素。实验结果表明,在操作压力为0.5MPa、废水温度为25~35℃、废水pH为7的条件下,NF-1#膜处理效果最佳,COD去除率最高,为76.0%~85.0%;脱盐率也最高,达90.0%。膜过滤后浓水送污水厂处理,产水回用于车间生产。操作压力增高、废水温度升高和废水pH增大均导致滤饼层阻力(Rc)和膜过滤过程中的总阻力(Rt)增加,Rc是Rt的主要组成部分,同时也是导致膜透过通量下降的主要因素。 相似文献